Publication:
Synthesis of Diphenyl Sulfide from Iodobenzene and Thiophenol using Metal Organic Framework Cu2(NDC)2(DABCO) as An Efficient Heterogeneous Catalyst

datacite.subject.fos oecd::Natural sciences
dc.contributor.author Nguyen Van Chi
dc.date.accessioned 2022-10-13T03:11:58Z
dc.date.available 2022-10-13T03:11:58Z
dc.date.issued 2020
dc.description.abstract A metal-organic framework Cu2(NDC)2(DABCO) was synthesized from copper nitrate trihydrate, 2,6-Napthalenedicarboxylic acid (H2NDC), and 1,4-diazabicyclo[2.2.2]octane (DABCO) by solvothermal method. Its physicochemical properties were confirmed by several techniques such as X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Cu2(NDC)2(DABCO) appeared as well-shaped crystals. To get diphenyl sulfide as desired product from the C-S cross coupling reaction of iodobenzene and thiophenol, the Cu2(NDC)2(DABCO) was used as heterogeneous catalyst in the presence of LiO-tBu as base. The results showed that the transformation could proceed with more than 93% reaction conversion being obtained after 6 h at 120 oC when using 5 mol% Cu2(NDC)2(DABCO) catalyst in the presence of LiO-tBu. The solid catalyst could be recovered and reused five times without a significant degradation in catalytic activity. The coupling reaction could only proceed to achieve major product in the presence of the Cu2(NDC)2(DABCO catalyst.
dc.identifier.uri http://repository.vlu.edu.vn:443/handle/123456789/251
dc.language.iso en_US
dc.relation.ispartof Vietnam Journal of Catalysis and Adsorption
dc.relation.issn 0866-7411
dc.subject C-S coupling
dc.subject iodobenzene
dc.subject LiO-t-Bu
dc.subject Cu2(NDC)2DABCO
dc.subject thiophenol
dc.title Synthesis of Diphenyl Sulfide from Iodobenzene and Thiophenol using Metal Organic Framework Cu2(NDC)2(DABCO) as An Efficient Heterogeneous Catalyst
dc.type Resource Types::text::journal::journal article
dspace.entity.type Publication
oaire.citation.endPage 76
oaire.citation.issue 8
oaire.citation.startPage 70
oaire.citation.volume 9
oairecerif.author.affiliation Van Lang University
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